Hot attraction in bimetals: A cyano-bridged vanadium-niobium bimetal assembly with a Curie temperature of 210 K
Cyano-bridged bimetal assemblies attract attention because of their magnetic properties such as photomagnetization, humidity-induced magnetization, and nonlinear magneto-optical effect, which make them suitable for many applications. A high Curie temperature is an asset for the use of such magnetic compounds in functional materials. Hexa-, hepta-, and octacyanometalates have been shown to have high Curie temperatures as a result of the high coordination number of their metal centers and the large superexchange interactions due to their diffuse 4d or 5d orbitals. Shin-ichi Ohkoshi and his co-workers at the University of Tokyo report the compound with the highest Curie temperature among octacyano-bridged bimetal assemblies in the Short Communication published in the European Journal of Inorganic Chemistry.