A step toward stronger polymers

Monday, November 5, 2012 - 20:30 in Physics & Chemistry

Many of the objects we encounter are made of polymers — long chains of repeating molecules. Networks of polymers form manmade materials such as plastics, as well as natural products such as rubber and cellulose. Within all of these polymeric materials, there are structural flaws at the molecular level. To form an ideal network, each polymer chain would bind only to another chain. However, in any real polymeric material, a significant fraction of the chains instead bind to themselves, forming floppy loops.“If your material properties depend on having polymers connected to each other to form a network, but you have polymers folded around and connected to themselves, then those polymers are not part of the network. They weaken it,” says Jeremiah A. Johnson, an assistant professor of chemistry at MIT.Johnson and his colleagues have now developed, for the first time, a way to measure how many loops are present in...

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