X-rays create a window on glass formation
Scientists have for the first time visualised the transformation of powder mixtures into molten glass. A better understanding of this process will make it possible to produce high quality glass at lower temperatures, leading to significant energy savings in industrial glass manufacturing. The results are published in the Journal of the American Ceramic Society. The team of scientists was led by Emmanuelle Gouillart from the joint research unit between CNRS and Saint Gobain, a global glass manufacturer, and included scientists from the Universities of Toulouse and Grenoble, INRIA Saclay and the European Synchrotron Radiation Facility (ESRF) in Grenoble.
Glass is one of the oldest human-made materials, use of which spread during ancient Egyptian and Roman cultures. A non-crystalline amorphous material, it is produced by the fusion of crystalline powder mixtures heated to high temperatures. These ingredients are quartz sand (silica, SiO2), sodium and calcium carbonates (Na2CO3, CaCO3), and minor more specific additives.
In industrial foundries, the powder mixture is heated to about 1500°C and kept at this elevated temperature for many days to eliminate bubbles and unmolten grains. This consumes a lot of energy and one of the current industrial challenges is obtaining glass of good quality at lower temperatures. For example, the global glass industry's energy consumption (86.5 TWh in 2005) compares with the entire electricity production of the Netherlands (108 TWh in 2008).
An individual grain of silica normally melts at very high temperatures (1700°C). Adding carbonates triggers chemical reactions that lower this temperature. However, the interplay between the geometry of the grains and the rate of chemical reactions during the early stages of the melting which starts already well below 1000°C, have remained a mystery to date.
The scientists set out to understand what exactly happens at the different stages of the transformation from powder to molten glass. For their experiment, they used mixtures of raw materials similar to that for making industrial window glass: two-thirds silica sand and one-third of sodium and calcium carbonates.
To make visible chemical reactions between individual grains, the scientists used X-ray microtomography, a technique allowing visualising in real time changes in shape and positions of all grains in a given volume. These changes are probed by a fine, intense beam of X-rays sent through the sample. Like a three-dimensional "frame by frame" sequence -- tiny variations of the transmitted X-ray intensity are recorded when sand and carbonate grains start to react chemically, changing their shapes and transforming themselves into molten glass. "At the ESRF, we can take a microtomography image with a spatial resolution of 1.6 micrometres every few seconds. Observing fast changes with a high spatial resolution deep inside an oven held at close to 1000°C is impossible without X-rays," says Marco Di Michiel from the ESRF.
The sequences of microtomography images confirmed the importance of good contact between grains of different substances, as it is these contacts which determine whether or not the mixture turns into liquid glass. For example, a calcium carbonate grain can either incorporate itself into the highly reactive amorphous liquid or remain a crystalline defect, depending on the presence or absence of such contacts. The researchers were surprised by the high reactivity of sodium carbonate when still solid: these grains move just before the melting begins which increases the number of contacts with other grains and facilitates the reactions.
By merging hundreds of X-ray tomography images, the scientists produced a video sequence visualising how different grains in the mixture move and fuse, one after the other, into molten glass as the temperature rose from 750°C to 930°C. "I have been working on these processes for many years, and it was absolutely fascinating to see like in a movie what happens at the onset of the powder/glass transition," says Emmanuelle Gouillart.
The scientists now wish to vary the sizes of the grains and the way in which they ramp up the temperature. In the long term, these fundamental studies will tell us how to reduce the number of defects produced at the start of the glass formation process, and help to find faster and less energy consuming manufacturing processes. "We also wish to make X-ray imaging methods and data analyses a routine visualisation tool for reactive granular mixtures. These are not only used in the manufacture of glass but also of other materials, and I see a huge industrial potential for optimising these processes," concludes Emmanuelle Gouillart.
- X-rays create a window on glass formation: First ever visualization of how powder becomes molten glassfrom PhysorgMon, 16 Apr 2012, 13:00:54 EDT
- Looking through the glass transition on an ultrafast timescalefrom PhysorgMon, 16 Apr 2012, 6:00:26 EDT
Latest Science NewsletterGet the latest and most popular science news articles of the week in your Inbox! It's free!
Check out our next project, Biology.Net
From other science news sites
Popular science news articles
- Using oxygen to sterilize medical implants could save time and money
- Influence of religion and predestination on evolution and scientific thinking
- Unique fragment from Earth's formation returns after billions of years in cold storage
- Gene therapy shows long-term benefit for treating rare blindness
- One-third of autistic children likely to wander, disappear
- Food allergies of low-income kids are poorly managed
- Contamination in North Dakota linked to fracking spills
- Coal-tar based sealcoats on driveways, parking lots far more toxic than suspected
- Hear no evil: Farmed fish found to be hard of hearing
- Silent epidemic? Head injury may be linked to lasting sleep problems
- Model makes designing new antennas orders of magnitude faster
- 1.5 C vs 2 C global warming: New study shows why half a degree matters
- Childhood obesity, malnutrition connected to mom's perception of child's weight
- Does a parent's perception of their child's weight impact on child weight gain?
- Paleontologists find first fossil monkey in North America -- but how did it get here?