Fine-tuned supramolecular polymerization
In nature, supramolecular complexes—chain-like structures that are composed of many small units linked mainly by weak non-covalent bonds—are assembled and disassembled in a precisely controlled way. Now, in work published in Science, researchers from the RIKEN Center for Emergent Matter Science, led by Takuzo Aida, have demonstrated a new method for artificially building and dismantling supramolecular polymers in a tightly controlled and selective way, following the methods of traditional polymer chemistry by taking advantage of the monomer elements' own tendency to self-organize. This opens the way to the creation, though precision supramolecular engineering, or polymers with a wide range of properties that could be exploited for new applications.