Theory models, EMSL capabilities illuminate how particles grow in the atmosphere
Determining the chemical mechanisms that govern new particle formation, or NPF, in the atmosphere is not something that can be pulled out of thin air. In the atmosphere, nucleating clusters are presumed to be composed of a few common species: sulfuric acid (the key chemical component), ammonia, amines (ammonia derivatives), and water—all of which have different effects on nucleation and particle growth. Moreover, these same clusters may significantly impact cloud condensation nuclei, the particles that spawn cloud formation, and, in turn, affect global climate. Scientists used EMSL's Fourier transform ion cyclotron resonance mass spectrometer equipped with surface-induced dissociation (SID) to examine and model fragmentation kinetics and energetics of small clusters that may serve as precursors to NPF.