Unique structural fluctuations at ice surface promote autoionization of water molecules

Monday, March 30, 2020 - 12:32 in Physics & Chemistry

Hydrated protons at the surface of water ice are of fundamental importance in a variety of physicochemical phenomena on earth and in the universe. Hydrated protons can be introduced by the autoionization of water molecules; thus, the autoionization and subsequent proton transfer processes determine the proton activity inherent to water molecular systems. A recent experimental study on the H/D isotopic exchange of water molecules reports markedly enhanced proton activity at the surface of crystalline ice.

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