New perspective for understanding the mechanisms of catalytic conversion

Wednesday, February 10, 2010 - 01:28 in Physics & Chemistry

The oxidation of toxic carbon monoxide (CO) to carbon dioxide occurs every day in millions of cars. Despite being one of the most studied catalytic processes, the exact mechanism of interaction between the carbon monoxide molecule and the catalyst, often platinum, is not fully understood. An important step in the reaction is the adsorption of CO on the surface of the catalyst. Scientists have now managed to see how the electrons in the platinum reorganize as the adsorption is taking place and why catalysts are “poisoned”, i.e. why their activity is reduced.

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