Swapping tellurium for sulfur improves light absorption in organic solar cells
Friday, February 6, 2015 - 08:00
in Physics & Chemistry
The investigation of light absorbing organic semiconductors is important for the development of lightweight flexible solar cells. Replacing sulfur atoms in commonly used, polymer-based solar cells with tellurium atoms results in materials that absorb a wider range of wavelengths of sunlight. A tellurophene-containing low-bandgap polymer (PDPPTe2T) was synthesized by microwave-assisted palladium-catalyzed ipso-arylative polymerization of 2,5-bis[(α-hydroxy-α,α-diphenyl)methyl]tellurophene with a diketopyrrolopyrrole (DPP) monomer.