Hybrid copper-gold nanoparticles convert CO2

Wednesday, April 11, 2012 - 03:30 in Physics & Chemistry

Copper — the stuff of pennies and tea kettles — is also one of the few metals that can turn carbon dioxide into hydrocarbon fuels with relatively little energy. When fashioned into an electrode and stimulated with voltage, copper acts as a strong catalyst, setting off an electrochemical reaction with carbon dioxide that reduces the greenhouse gas to methane or methanol. Various researchers around the world have studied copper’s potential as an energy-efficient means of recycling carbon dioxide emissions in powerplants: Instead of being released into the atmosphere, carbon dioxide would be circulated through a copper catalyst and turned into methane — which could then power the rest of the plant. Such a self-energizing system could vastly reduce greenhouse gas emissions from coal-fired and natural-gas-powered plants.But copper is temperamental: easily oxidized, as when an old penny turns green. As a result, the metal is unstable, which can significantly slow its...

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